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First name, Middle name, Last name, Scientific degree, Scientific rank, Current position. Full and brief name of the organization, The organization address.Barysheva O.B. – candidate of technical sciences, associate professor E-mail: This e-mail address is being protected from spambots. You need JavaScript enabled to view it Khabibullin Iu.Kh. – candidate of technical sciences, associate professor E-mail: This e-mail address is being protected from spambots. You need JavaScript enabled to view it Kazan State University of Architecture and Engineering The organization address: 420043, Russia, Kazan, Zelenaya st., 1
Title of the articleNumerical simulation of combustion parameters settings based on the kinetics of chemical reactions
Abstract.This work presents the numerical research aimed at solving the problem of determining the parameters of the combustion of municipal solid waste, taking into account the formation of polychlorinated dioxins precursors. The basic information about the accepted method for determining is non-equilibrium composition of the combustion products of chlorine-containing chemical fuels. A significant decrease in the yield of dioxins can be obtained by pre-gasification of municipal solid waste and subsequent purification of the product gas. The gas can be burned in various combustion plants, and condensed substances produced during gasification of municipal solid waste exported for disposal or use in secondary production (binders). Based on analysis of the literature on the works and rates of chemical reactions, reactions of chlorine compounds а kinetic model for the formation of dioxin precursors. Earlier calculations assuming chemical equilibrium showed that the formation of dioxins is non-equilibrium. The results of kinetic studies on emissions of dioxin precursors showed the variation of various components of the combustion of municipal solid waste time for different temperature levels.
Keywords.polychlorinated dioxins, precursors, kinetics, equilibrium, none equilibrium, modeling, halogens.
For citations:Barysheva O.B., Khabibullin Iu.Kh. Numerical simulation of combustion parameters settings based on the kinetics of chemical reactions // Izvestiya KGASU. 2015. №2(32) P.380-385.


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